tooluniverse-inorganic-physical-chemistry

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Inorganic chemistry, physical chemistry, and materials science — crystal structures, coordination chemistry, bonding theory (covalency, orbital mixing), symmetry/point groups, thermodynamics, kinetics, spectroscopy interpretation, noble gas compounds, lanthanide/actinide chemistry. Use for questions about crystal systems, unit cells, density calculations, metal complexes, solid-state chemistry, or physical chemistry calculations.

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Sourcemims-harvard/tooluniverse

Added on2026-05-11

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SKILL.md Content

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Inorganic & Physical Chemistry

Reasoning Strategy

1. Crystal Structure Questions

When given crystal structure data, always COMPUTE don't guess:

Calculate unit cell volume for the crystal system:
- Cubic: V = a^3
- Tetragonal: V = a^2 * c
- Orthorhombic: V = a * b * c
- Monoclinic: V = a * b * c * sin(beta)
- Triclinic: V = abc * sqrt(1 - cos^2(alpha) - cos^2(beta) - cos^2(gamma) + 2*cos(alpha)*cos(beta)*cos(gamma))
- Hexagonal: V = a^2 * c * sqrt(3)/2
Verify density: d = (Z * M) / (V * Na * 1e-24) where V in Å³, M in g/mol, Na = 6.022e23

Preferred: Use

CrystalStructure_validate

tool (via MCP/SDK). Fallback:

python3 skills/tooluniverse-organic-chemistry/scripts/crystal_validator.py --a X --b Y --c Z --alpha A --beta B --gamma G --Z N --MW M --density D

For batch comparison (find the wrong dataset): Save datasets as JSON array and use
```
--datasets path/to/datasets.json
```

2. Bonding & Covalency Questions

Key reasoning patterns:

Covalency = orbital mixing between metal and ligand. Greater overlap = more covalent.
Lanthanide/actinide: 4f orbitals of Ce(IV) typically show ENHANCED covalent mixing vs Ce(III) — more contracted 4f in higher oxidation states increases overlap with ligand orbitals
But: Enhanced covalency does NOT always mean stronger bonds — it depends on the specific orbital interactions
d-block vs f-block: d-orbitals have more radial extension → stronger covalent bonds than f-orbitals
Nephelauxetic effect: Reduced electron-electron repulsion in complexes → indicates covalency. Larger effect = more covalent.

3. Noble Gas Chemistry

Xe compounds: XeF2 (linear), XeF4 (square planar), XeF6 (distorted octahedral)
XeF4 synthesis: Requires Xe + F2 at elevated temperature (400°C) and pressure. Can also form at lower temperatures with specific methods (UV photolysis, electric discharge)
Key: Temperature thresholds matter for synthesis efficiency. LOOK UP DON'T GUESS — search literature for specific synthesis conditions.

4. Symmetry & Point Groups

Identify the molecular shape
Find symmetry elements: C_n axes, mirror planes (σ_h, σ_v, σ_d), inversion center (i), improper rotation (S_n)

Use

python3 skills/tooluniverse-organic-chemistry/scripts/chemistry_facts.py point_groups

for point group lookup

Optical activity: Requires absence of improper rotation axes (S_n, including σ = S_1 and i = S_2). Chiral point groups: C_1, C_n, D_n, T, O, I
Crystal classes with optical activity: Piezoelectric non-centrosymmetric classes that lack mirror planes and inversion

5. Thermodynamics & Kinetics

COMPUTE DON'T ESTIMATE — write Python code for:

Gibbs free energy: ΔG = ΔH - TΔS
Equilibrium constant: K = exp(-ΔG/RT)
Arrhenius equation: k = A * exp(-Ea/RT)
Nernst equation: E = E° - (RT/nF) * ln(Q)
Clausius-Clapeyron: ln(P2/P1) = -ΔH_vap/R * (1/T2 - 1/T1)

6. Solubility & Equilibrium Calculations

Preferred: Use

EquilibriumSolver_calculate

tool (via MCP/SDK) with

type

,

ksp

,

stoich

, and other parameters. Fallback: run

equilibrium_solver.py

directly.

bash

# Simple Ksp: MaXb(s) <-> aM + bX
python3 skills/tooluniverse-inorganic-physical-chemistry/scripts/equilibrium_solver.py \
  --type ksp_simple --ksp 5.3e-27 --stoich 1:3

# Ksp + complex formation (e.g., Al(OH)3 in water with Al(OH)4- complex)
python3 skills/tooluniverse-inorganic-physical-chemistry/scripts/equilibrium_solver.py \
  --type ksp_kf --ksp 5.3e-27 --kf 1.1e33 --stoich 1:3

# Common ion effect (e.g., AgCl in 0.1M NaCl)
python3 skills/tooluniverse-inorganic-physical-chemistry/scripts/equilibrium_solver.py \
  --type common_ion --ksp 1.77e-10 --stoich 1:1 --common-ion 0.1

Key points:

```
ksp_kf
```
mode solves the full charge-balance system numerically (Newton's method) — accounts for free cation, complex anion, and OH-/H+ simultaneously
For
```
MX_b + X- <-> MX_(b+1)-
```
, K_overall = Ksp * Kf
```
common_ion
```
mode uses bisection to solve the exact Ksp expression with extra ion concentration
Always specify
```
--stoich a:b
```
matching the salt formula (e.g., 1:3 for Al(OH)3, 1:2 for CaF2, 1:1 for AgCl)

7. Spectroscopy Interpretation

UV-Vis: d-d transitions (weak, Laporte forbidden), LMCT/MLCT (strong), π→π* (organic)
IR: Functional group region (4000-1500 cm⁻¹), fingerprint (1500-400 cm⁻¹)
NMR: Chemical shift indicates electronic environment. For counting peaks, identify symmetry-equivalent protons.
For peak counting: Draw the structure, identify all symmetry operations, group equivalent H atoms. Use
```
python3 skills/tooluniverse-organic-chemistry/scripts/chemistry_facts.py
```
for reference data.

Available Tools

Tool	Use For
`PubChem_get_CID_by_compound_name`	Get compound CID from name
`PubChem_get_compound_properties_by_CID`	Detailed compound data by CID
`ChEMBL_search_molecules`	Bioactive compounds
`PubMed_search_articles`	Literature on synthesis conditions, properties
`CrystalStructure_validate` tool (or `crystal_validator.py` fallback)	Verify crystal structure data consistency
`EquilibriumSolver_calculate` tool (or `equilibrium_solver.py` fallback)	Ksp, complex formation, common-ion solubility

LOOK UP DON'T GUESS

Noble gas compound synthesis conditions vary by method — search literature before answering
Crystal structure parameters must be computed, not estimated
Bonding descriptions (covalent vs ionic) require specific orbital considerations — don't generalize from one system to another